Research Summary

Photon is one type of the fundamental carriers of energy, entropy, and momentum. My research interests are experimental and theoretical understanding of photonic transport processes in different regimes. These regimes include near- and far-field, thermal equilibrium and non-equilibrium, and reciprocal and nonreciprocal. These transport processes could enable functionalities that are difficult to find in electronic and phononic transport processes and may provide fundamentally new solutions in thermal management and energy conversion.

To be specific, one primary research direction I have worked on is micro/nanoscale thermal radiation, which concerns electromagnetic wave interactions with micro/nanostructured materials that could potentially modify the far-field radiative properties, near-field radiative heat transfer between closely spaced objects, and radiative interactions between photons with nonzero chemical potential. My research shows that plasmonic subwavelength nanostructures and metamaterials can exploit plasmons, a collective oscillation of charge carriers, to achieve wavelength-selective thermal radiation in the far-field. Two-dimensional (2D) materials, such as graphene, hexagonal boron nitride (hBN), and black phosphorus (BP), offer new exciting elements to construct metamaterials with unique thermal radiative properties. Meanwhile, my research on the near-field heat transfer and enhanced photon tunneling between 2D materials (heterostructures), micro/nanostructures, and metamaterials are of critical importance for energy harvesting, Super-Planckian radiative heat transfer, near-field imaging systems, scanning-tunning microscopy, and data storage.

The other primary research direction I have worked on is photonic heat engines and refrigerators. In the past, I proposed or worked on several types of photonic heat engines. Some of them are still holding the current records for power densities or conversion efficiencies. I have also proposed the first electronic circuit that allows thermophotonic systems to run self-sustainingly, which shows that electronic circuits can do nontrivial things in energy applications.

My major published works are listed below. You may find that they are related to areas including Near- and Far-Field Thermal Radiation, Nanophotonics, Electronic Circuits, Energy Harvesting, Plasmonics, 2D Materials, and Numerical Design.

Chemical Potential for Photons and Its Implications for Controlling Radiative Heat Transfer

In conventional photon-based heat transfer, one typically assumes that the chemical potential of photons is zero. On the other hand, when a semiconductor is under external biases, the photons with energy above the semiconductor bandgap can exhibit a non-zero chemical potential that is proportional to the applied voltage. The presence of such non-zero chemical potential points to the abilities to drastically enhance the power density of photon-based heat flow, to electronically control photon-based heat transfer, and to construct photon-based heat engines for energy harvesting and solid-state cooling. Here we discuss basic concepts and applications of chemical potential for photons in controlling radiative heat transfer. Invited Review for Annual Review of Heat Transfer, processing.

Near-Complete Violation of Kirchhoff's Law of Thermal Radiation with a 0.3-Tesla Magnetic Field

The capability to overcome Kirchhoff’s law of thermal radiation provides new opportunities in energy harvesting and thermal radiation control. Previously design towards demonstrating such capability requires a magnetic field of 3 Tesla, which is difficult to achieve in practice. In this work, we propose a nanophotonic design that can achieve such capability with a far more modest magnetic field of 0.3 Tesla, a level that can be achieved with permanent magnets. Our design uses guided resonance in low-loss dielectric gratings sitting on a magneto-optical material, which provides significant enhancement on the sensitivity to the external magnetic field. Related Paper

Self-Sustaining Thermophotonic Circuits

Photons represent one of the most important heat carriers. The ability to convert photon heat flow to electricity is therefore of substantial importance for renewable energy applications. However, photon-based systems that convert heat to electricity, including thermophotovoltaic systems where photons are generated from passive thermal emitters, have long been limited by low power density. This limitation persists even with near-field enhancement techniques. Thermophotonic systems, which utilize active photon emitters such as light emitting diodes, have the potential to significantly further enhance the power density. However, this potential has not been realized in practice, due in part to the fundamental difficulty in thermodynamics of designing a self-sustaining circuit that enables steady-state power generation. Here, we overcome such difficulty by introducing a configuration where the light emitting diodes are connected in series, and thus multiple photons can be generated from a single injected electron. As a result we propose a self-sustaining thermophotonic circuit where the steady-state power density can exceed thermophotovoltaic systems by many orders of magnitude. This work points to new possibilities for constructing heat engines with light as the working medium. The flexibility of controlling the relations between electron and photon flux, as we show in our design, may also be of general importance for optoelectronics-based energy technology. Related Paper

Near-Field Thermophotonic Systems for Low-Grade Waste Heat Recovery

Low-grade waste heat contains an enormous amount of exergy that can be recovered for renewable energy generation. Current solid-state techniques for recovering low-grade waste heat, such as thermoelectric generators and thermophotovoltaics, however, are limited by low conversion efficiencies or power densities. In this work, we propose a solid-state near-field thermophotonic system. The system consists of a light emitting diode (LED) on the hot side and a photovoltaic (PV) cell on the cold side. Part of the generated power by the PV cell is used to positively bias the LED. When operating in the near-field regime, the system can have power density and conversion efficiency significantly exceeding the performance of current solid-state approaches for low-grade waste heat recovery. For example, when the gap spacing is 10 nm and the hot side and cold side are respectively at 600 K and 300 K, we show that the generated electric power density and thermal-to-electrical conversion efficiency can reach 9.6 W/cm2 and 9.8 %, respectively, significantly outperforming the current record-setting thermoelectric generators. We identify the alignment of the bandgaps of the LED and the PV cell, the appropriate choice of thickness of the LED and PV cell to mitigate the effect of non-radiative recombination, and the use of highly reflective back mirrors as key factors that affect the performance of the system. Our work points to the significant potential of photonic systems for the recovery of low-grade waste heat. Related Paper

High-Performance Near-field Thermophotovoltaics for Waste Heat Recovery

The US industries reject nearly 20%-50% of the consumed energy into the environment as waste heat. Harvesting this huge amount of heat can substantially improve the energy usage efficiency. For waste heat in the medium temperature range (~500-900 K), traditional solid-state waste heat recovery techniques like thermoelectric generators and thermophotovoltaics (TPVs) are still suffering from relatively low efficiency or power density. In this work, we analyze a near-field TPV system consisting of a plasmonic emitter (indium tin oxide) and a narrow-bandgap photovoltaic cell (InAs) that are brought to deep sub-wavelength distances for high-efficiency and high-power-density waste heat recovery. We show that despite the inclusion of realistic nonradiative recombination rates and sub-bandgap heat transfer, such a near-field TPV system can convert heat to electricity with up to 40% efficiency and 11 W/cm2 power density at a 900 K emitter temperature, because of the spectral reshaping and enhancement by the thermally excited surface plasmons and waveguide modes. Thus, we show that for waste heat recovery, near-field TPV systems can have performances that significantly exceed typical thermoelectric systems. We propose a modified system to further enhance the power density by using a thin metal film on the cell, achieving a counterintuitively “blocking-assisted” heat transfer and power generation in the near-field regime. Related Paper

Strong Near-Field Radiative Heat Transfer between Doped-Si Parallel Plates

Heat transfer between two objects separated by a nanoscale vacuum gap holds great promise especially in energy harvesting applications such as near-field thermophotovoltaic systems. However, experimental validation of nanoscale radiative heat transfer has been largely limited to tip-plate configurations due to challenges of maintaining small gap spacing over a relatively large area. Here, we report measurements of heat transfer near room temperature between two 1 cm by 1 cm doped-Si parallel plates, separated by a vacuum gap from 200 nm to 782 nm. The measured strong near-field radiative transfer is in quantitative agreement with the theoretical prediction based on fluctuational electrodynamics. The largest measured radiative heat flux is 11 times as high as the blackbody limit for the same hot and cold surface temperatures. Our experiments have produced the highest radiative heat transfer rate observed to date across submicron distances between objects near room temperature. Related Paper

Thermophotovoltaic Emitters Based on a Two-dimensional Grating/Thin-Film Nanostructure

Thermophotovoltaic (TPV) devices can convert thermal radiation directly into electricity. To improve the efficiency of TPV systems, wavelength-selective emitters are designed to take thermal energy from various heat sources and then emit photons to the TPV cells. This work proposes a two-dimensional grating/thin-film nanostructure as an efficient emitter, whose performance is enhanced by the excitations of both surface plasmon polaritons (SPPs) and magnetic polaritons (MPs). The normal emittance of the proposed nanostructure is shown to be wavelength-selective and polarization-insensitive. The mechanisms of SPP and MP excitations in the nanostructure are elucidated for different polarizations. The effect of azimuthal and polar angles on the emittance spectra suggests that the proposed structure has high emittance not only in the normal direction but also at large oblique angles.Related Paper

Magnetic Polaritons in Deep Metallic Gratings

This work reveals the fundamental mechanism for the resonances in deep gratings by considering the excitation of magnetic polaritons (MPs). It is shown that MPs and cavity modes agree with each other when the kinetic inductance is negligibly small. However, when the kinetic inductance is sufficiently large, the maximum resonance wavelength can be more than twice that predicted by the cavity mode. Different materials are considered and the frequency range is extended from the near-infrared to the microwave region to illustrate the scalability of the MPs. This study clarifies one of the underlying mechanisms of optical resonance in deep gratings and can benefit the design of wavelength-selective thermal emitters. Related Paper

Enhanced Absorption in Graphene With Metal Gratings

Graphene has been demonstrated as a good candidate for ultrafast optoelectronic devices. However, graphene is essentially transparent in the visible and near infrared with an absorptivity of 2.3%, which has largely limited its application in photon detection. This work demonstrates that the absorptance in a monatomic graphene layer can be greatly enhanced to nearly 70%, thanks to the localized strong electric field resulting from magnetic resonances in deep metal gratings. Furthermore, the resonance frequency is essentially not affected by the additional graphene layer. This method may benefit the design of next-generation graphene-based optical and optoelectronic devices.Related Paper

Strong Plasmonic Coupling between Graphene Ribbon Array and Metal Gratings

The collective oscillation of the massless electrons in graphene ribbons can interact with photons to create graphene plasmon polaritons. The resonance-induced absorption is critical in signal detection and energy harvesting applications. However, because of their atomic thickness, high absorptance is difficult to achieve with graphene ribbons alone. In this work, a hybrid plasmonic system composed of an array of graphene ribbons over a periodic metal grating is theoretically investigated. It is shown that the localized resonances, i.e., magnetic polaritons, in metal gratings can couple with the plasmonic resonance in graphene ribbons, resulting in significantly enhanced absorption in graphene. Moreover, the coupling phenomenon depends on the width of the ribbons and the relative positions of the ribbon and the grating. The coupling between the grating and a continuous graphene monolayer sheet is also investigated and the results are compared to those with graphene ribbons. The findings of this work may facilitate the design of optoelectronic devices and metamaterials structures based on hybrid nanostructures and graphene.Related Paper

Enhanced Photon Tunneling by Surface Plasmon-Phonon Polaritons in Graphene/hBN Heterostructures

Enhancing photon tunneling probability is the key to increasing the near-field radiative heat transfer between two objects. It has been shown that hexagonal boron nitride (hBN) and graphene heterostructures can enable plentiful phononic and plasmonic resonance modes. This work demonstrates that heterostructures consisting of a monolayer graphene on a hBN film can support surface plasmon-phonon polaritons that greatly enhance the photon tunneling and outperform individual structures made of either graphene or hBN. Both the thickness of the hBN films and the chemical potential of graphene can affect the tunneling probability, offering potential routes toward passive or active control of near-field heat transfer. The results presented here may facilitate the system design for near-field energy harvesting, thermal imaging, and radiative cooling applications based on two-dimensional materials.Related Paper

Perfect Mid-Infrared Absorption by Hybrid Phonon-Plasmon Polaritons in hBN/Metal Grating Anisotropic Structures

The ability to support low-loss hyperbolic phonon-polaritons (HPP) by hexagonal boron nitride (hBN) films has attractive potentials for achieving perfect absorption and wavelength-selective emission for high-temperature applications. A nanostructure based on periodic metal gratings and hBN films is proposed here. As a phononic two-dimensional (2D) material, hBN has two mid-infrared Reststrahlen bands with natural hyperbolic responses. Magnetic polaritons (MP) in metal gratings can couple with HPPs in hBN to create hybrid hyperbolic phonon-plasmon polaritons, resulting in perfect or near-perfect absorption. It is found that the majority of the power absorbed by the hybrid polaritons is dissipated in the hBN film with a unique tunable location-dependent absorption profile. Meanwhile, in the frequency range where hBN does not support HPPs, optical phonons in hBN can still couple with MPs in gratings to yield resonance absorption. The effect of geometric parameters is analyzed to elucidate the mechanisms of the perfect and near-perfect absorption. The radiative properties and dissipation profiles are calculated based on rigorous coupled-wave analysis, which has been extended to include anisotropic materials. This work reveals the promising potential of using 2D materials and nanostructures to achieve unique radiative properties. The results from this work may benefit applications such as energy harvesting, radiative cooling, and photodetection.Related Paper